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GET COATEDFX- 100info@FlexRockCoatings.com | 800-808-0414 | FlexRockCoatings.comSAFETY DATA SHEET
www.flexrockcoatnings.com | 800.808.0414info@flexrockcoatnings.comFlexRock Coatings™ Part A Page 1Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART A1. PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME: FlexRock Coatings™, Part A PRODUCT NUMBER: FX-100-ARECOMMENDED USE: Industrial coating ingredientMANUFACTURER/SUPPLIER1040 S. Gaylord St. Suite 55Denver, CO 8020924 HR EMERGENCY TELEPHONE NUMBERS Emergency Contact Number : 800-808-0414 Non-Emergency Phone Number: 800-808-04142. HAZARDS IDENTIFICATIONClassication of the Substance or Mixture Classication(GHS-US) Eye Irritant 2B H320Label ElementsGHS-US LabelingSignal Word (GHS-US): WarningHazard Statements (GHS-US): H320 - Causes eye irritationPrecautionary Statements (GHS-US): P264 - Wash exposed areas thoroughly after handling. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention.3. COMPOSITION/INFORMATION ON INGREDIENTSWt% CAS#30-60 8001-79-430-60 13397-24-5Chemical Name Plant Based Oil Calcium Sulfate Dihydrate Trade Secret 1-5 -Issue Date: January 2019 | Updated: January 2021
www.flexrockcoatnings.com | 800.808.0414info@flexrockcoatnings.comFlexRock Coatings™ Part A Page 2Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART A4. FIRST AID MEASURESDescription of First Aid Measures• First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice(show the label where possible).• First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area.• First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes.• First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easyto do. Continue rinsing.• First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting.Most important symptoms and effects, both acute and delayed• Symptoms/Injuries: Eye irritation.• Symptoms/Injuries After Inhalation: Not expected to present a signicant inhalation hazard under anticipated conditions of normal use.• Symptoms/Injuries After Skin Contact: None under normal conditions.• Symptoms/Injuries After Eye Contact: Causes eye irritation.• Symptoms/Injuries After Ingestion: If a large quantity has been ingested: May cause nausea, vomiting, and diarrhea.Indication of Any Immediate Medical Attention and Special Treatment Needed• If medical advice is needed, have product container or label at hand.5. FIRE FIGHTING MEASURESExtinguishing Media• Suitable Extinguishing Media: Alcohol foam, dry chemical, carbon dioxide, water spray, fog.• Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread re.Special Hazards Arising From the Substance or Mixture• Fire Hazard: Not ammable.• Explosion Hazard: Product is not explosive.• Reactivity: Stable at ambient temperature and under normal conditions of use.Advice for Fireghters• Firefighting Instructions Exercise caution when ghting any chemical re.• Protection During Firefighting Do not enter re area without proper protective equipment, including respiratory protection.www.FlexRockCoatings.com | 800.808.0414 |info@FlexRockCoatings.com
www.flexrockcoatnings.com | 800.808.0414info@flexrockcoatnings.comFlexRock Coatings™ Part A Page 3Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART A6. ACCIDENTAL RELEASE MEASURESPersonal Precautions, Protective Equipment and Emergency Procedures• General Measures: Caution : this product can cause the oor to be very slippery.For Non-emergency Personnel• Protective Equipment: Use appropriate personal protection equipment (PPE).• Emergency Procedures: Evacuate unnecessary personnel.For Emergency Responders• Protective Equipment: Equip cleanup crew with proper protection.• Emergency Procedures: Ventilate area.Environmental Precautions• Prevent entry to sewers and public waters.Methods and Material for Containment and Cleaning Up• For Containment: Absorb and/or contain spill with inert material, then place in suitable container.• Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely.Reference to Other SectionsSee heading 8, Exposure Controls and Personal Protection.7. HANDLING AND STORAGEHANDLING: MIX WELL BEFORE USE• Provide suitable extraction/ventilation at processing machines and avoid skin/eye contact.STORAGE: Keep container in cool well-ventilated place. Keep containers tightly closed.• Storage Period: 12 MonthsPrecautions for Safe Handling• Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areaswith mild soap and water before eating, drinking, or smoking and again when leaving work. Do not eat, drink or smoke when usingthis product.Conditions for Safe Storage, Including Any Incompatibilities• Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use.• Incompatible Products: Strong oxidizers.• Storage Temperature: In bulk, store at about 5-10°C above melting point or at ambient temperature.• Storage Area: Temperature higher than necessary degrades quality at rates dependent on time and temperature of exposure.
www.flexrockcoatnings.com | 800.808.0414 |info@flexrockcoatnings.comFlexRock Coatings™ Part A Page 4Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART A8. EXPOSURE CONTROLS / PERSONAL PROTECTIONControl Parameters• No Occupational Exposure Limits (OELs) have been established for this product or its chemical components.Exposure Controls• Personal Protective Equipment: Gloves. Safety glasses.• Hand Protection: Wear chemically resistant protective gloves. The breakthrough time of the selected gloves must be greater than theintended use period.• Eye Protection: Chemical goggles or safety glasses.• Respiratory Protection: In case of inadequate ventilation wear respiratory protection.• Other Information: When using, do not eat, drink or smoke.9. PHYSICAL AND CHEMICAL PROPERTIESFLASH POINT, METHOD: 229˚C (c.c.)• PHYSICAL STATE: Liquid/solid suspension• ODOR: Oily• COLOR: Varied• pH: Not applicable• PERCENT VOLATILE: Not Determined• VAPOR DENSITY: Heavier than air• BOILING POINT: > 300 °C (572°F)• MELTING POINT: Not Determined• SOLUBILITY IN WATER: Insoluble• ENTHALPY OF VAPORIZATION: Not Determined• SPECIFIC GRAVITY: 1.2• VISCOSITY: Not Determined10. STABILITY AND REACTIVITYSTABLE: Chemically stable under normal and anticipated storage and handling conditions.• HAZARDOUS POLYMERIZATION: No.• HAZARDOUS COMBUSTION PRODUCTS: Black smoke, oxides of carbon, oxides of sulfur.• CONDITIONS TO AVOID: None• INCOMPATIBLE MATERIALS: Strong oxidizers
www.flexrockcoatnings.com | 800.808.0414info@flexrockcoatnings.comFlexRock Coatings™ Part A Page 5Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART A11. TOXICOLOGICAL INFORMATIONInformation On Toxicological Effects• Acute Toxicity: Not classied• Skin Corrosion/Irritation: Not classied• Serious Eye Damage/Irritation: Causes eye irritation.• Respiratory or Skin Sensitization: Not classied• Germ Cell Mutagenicity: Not classied• Carcinogenicity: Not classied• Reproductive Toxicity: Not classied• Specific Target Organ Toxicity (Single Exposure): Not classied• Specific Target Organ Toxicity (Repeated Exposure): Not classied• Aspiration Hazard: Not classied• Symptoms/Injuries After Inhalation: Not expected to present a signicant inhalation hazard under anticipated conditions of normal use.• Symptoms/Injuries After Skin Contact: None under normal conditions.• Symptoms/Injuries After Eye Contact: Causes eye irritation.• Symptoms/Injuries After Ingestion: If a large quantity has been ingested: May cause nausea, vomiting, and diarrhea.12. ECOLOGICAL INFORMATIONGENERAL COMMENTS: Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.• Toxicity. No additional information available.Persistence and Degradability• Castor Oil: Persistence and degradability not established.Bioaccumulative Potential• Castor Oil: Bioaccumulative potential not established.Mobility in Soil. • No additional information availableOther Adverse Effects• Other Information: Avoid release to the environment.13. DISPOSAL CONSIDERATIONSDISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations.• PRODUCT DISPOSAL: In accordance with local authority regulations, take to special waste incineration plant.• EMPTY CONTAINER DISPOSAL: If empty contaminated containers are recycled or disposed of, the receiver must be informed aboutpossible hazards.
www.flexrockcoatnings.com | 800.808.0414info@flexrockcoatnings.comFlexRock Coatings™ Part A Page 6Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART A14. TRANSPORT INFORMATIONDOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Not Regulated• PRIMARY HAZARD CLASS/DIVISION: N/A• UN/NA NUMBER: N/A• PACKING GROUP: N/A15. REGULATORY INFORMATIONUNITED STATES: OSHA HAZARD COMMUNICATION STANDARD• This product is Not Hazardous as defined y the OSHA Hazard Communication Standard.SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)• 311/312 HAZARD CATEGORIES: FIRE: NO• REACTIVITY: NO• ACUTE: YES• 313 REPORTABLE INGREDIENTS: This product contains no SARA Title III, Section 313 listed chemicals.PENNSYLVANIA RIGHT TO KNOW COMPONENTS • Plant Based Oil 8001-79-4• Calcium Sulfate dihydrate 13397-24-5NEW JERSEY RIGHT TO KNOW COMPONENTS• Plant Base Oil: 8001-79-4• Calcium Sulfate dihydrate: 13397-24-5MASSACHUSETTS RIGHT TO KNOW COMPONENTS• Calcium Sulfate dihydrate: 13397-24-5TSCA (TOXIC SUBSTANCE CONTROL ACT)• TSCA REGULATORY: All intentional ingredients are listed in the TSCAInventory.16. OTHER INFORMATIONPREPARED BY: GreenKoat Solutions, LLC.DATE: Updated January 2021 MANUFACTURER DISCLAIMER: The information contained herein is based on data believed to be reliable by GreenKoat Solutions, LLC. It is true and accurate to the best of our knowledge, but is not intended to be all inclusive. Users should consider this information as a supplement to other information gathered by them and must make their own determination of suitability and completeness to assure proper safe use and disposal of these materials.
GreenKoat™ Part B Page 1Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BSignal word: DANGER!HazardsIssue DaSafety Data Sheet GreenKoat, Part BIssue date April 18, 20191. PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME: FlexRock Coatings™, Part BPRODUCT NUMBER: GK101-BRECOMMENDED USE: Industrial coating ingredientMANUFACTURER/SUPPLIERGreenKoat Solutions, LLC1040 S Gaylord St. Suite 55Denver, CO 8020924 HR EMERGENCY TELEPHONE NUMBERSEmergency Contact Number : 800.808.0414Non-Emergency Phone Number: 800.808.04142. HAZARDS IDENTIFICATIONHazard classicationGHS classication in accordance with 29 CFR 1910.1200Acute toxicity - Category 4 - InhalationSkin irritation - Category 2Eye irritation - Category 2BRespiratory sensitisation - Category 1Skin sensitisation - Category 1Specic target organ toxicity - single exposure - Category 3Specic target organ toxicity - repeated exposure - Category 2 - InhalationLabel elementsHazard pictogramste: January 2019 | Updated: March 2019www.FlexRockCoatings.com | 800.808.0414 |info@FlexRockCoatings.com
GreenKoat™ Part B Page 2Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BCauses skin and eye irritation.May cause an allergic skin reaction. Harmful if inhaled.May cause allergy or asthma symptoms or breathing difculties if inhaled. May cause respiratory irritation.May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.Precautionary statementsPrevention• Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.• Wash skin thoroughly after handling.• Use only outdoors or in a well-ventilated area.• Contaminated work clothing should not be allowed out of the workplace.• Wear protective gloves.• In case of inadequate ventilation wear respiratory protection.Response• IF ON SKIN: Wash with plenty of soap and water.• IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.• IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.• If skin irritation or rash occurs: Get medical advice/ attention.• If eye irritation persists: Get medical advice/ attention.• If experiencing respiratory symptoms: Call a POISON CENTER/doctor. Take off contaminated clothing and wash before reuse.Storage• Store in a well-ventilated place. Keep container tightly closed.• Store locked up.Disposal• Dispose of contents/ container to an approved waste disposal plant.3. COMPOSITION / INFORMATION ON INGREDIENTSSynonyms: Polymeric diphenylmethane diisocyanateChemical Name Wt % #CAS #EINECSDiphenylmethane Diisocyanate, 99 – 100 9016-87-9 N/A isomers and homologues 4,4’ –Methylenediphenyl diisocyanate 30 – 50% 101-68-8 N/A*CAS 101-68-8 is an isomer of CAS 9016-87-9
FlexRock Coatings™ Part B Page 3Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART B4. FIRST AID MEASURESGeneral advice:First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specic personal protective equipment.Inhalation: Move person to fresh air. If not breathing, give articial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difcult, oxygen should be administered by qualied personnel. Call a physician or transport to a medical facility.Skin contact: Remove material from skin immediately by washing with soap and plenty of water. Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists. Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be available in work area.Eye contact: Immediately ush eyes with water; remove contact lenses, if present, after the rst 5 minutes, then continue ushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available.Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.Most important symptoms and effects, both acute and delayed:Aside from the information found under Description of rst aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information.Indication of any immediate medical attention and special treatment neededNotes to physician: Maintain adequate ventilation and oxygenation of the patient. May cause respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving signicant exposure should be observed 24-48 hours for signs of respiratory distress. If you are sensitized to diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. Excessive exposure may aggravate preexisting asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome).
FlexRock Coatings™ Part B Page 4Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART B5. FIRE FIGHTING MEASURESSuitable extinguishing media: Water fog or ne spray. Dry chemical re extinguishers. Carbon dioxide re extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.Unsuitable extinguishing media: Do not use direct water stream. May spread re.Special hazards arising from the substance or mixtureHazardous combustion products: During a re, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen cyanide. Carbon monoxide. Carbon dioxide.Unusual Fire and Explosion Hazards: Material reacts slowly with water, releasing carbon dioxide which can cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this reaction. Container may rupture from gas generation in a re situation. Violent steam generation or eruption may occur upon application of direct water stream to hot liquids. Dense smoke is produced when product burns.Advice for reghtersFire Fighting Procedures: Keep people away. Isolate re and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not recommended, but may be applied in large quantities as a ne spray when other extinguishing agents are not available. Do not use direct water stream. May spread re. Fight re from protected location or safe distance. Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from venting safety device or discoloration of the container. Move container from re area if this is possible without hazard. Use water spray to cool re-exposed containers and re-affected zone until re is out. Contain re water run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the “Accidental Release Measures” and the “Ecological Information” sections of this (M)SDS.Special protective equipment for reghters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective re ghting clothing (includes re ghting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during re ghting operations. If contact is likely, change to full chemical resistant re ghting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and ght re from a remote location. For protective equipment in post-re or non-re clean-up situations, refer to the relevant sections.
FlexRock Coatings™ Part B Page 5Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART B6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate area of leak or spill. If available, use foam to smother or suppress. Refer to section 7, Handling, for additional precautionary measures. See Section 10 for more specic information. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Contain spilled material if possible.Absorb with materials such as: Dirt. Vermiculite. Sand. Clay. Do NOT use absorbent materials suchas: Cement powder (Note: may generate heat). Collect in suitable and properly labeled open containers. Do not place in sealed containers. Suitable containers include: Metal drums. Plastic drums. Polylined ber pacs. Wash the spill site with large quantities of water. Attempt to neutralize by adding suitable decontaminant solution: Formulation 1: sodium carbonate 5 - 10%; liquid detergent 0.2 - 2%; water to make up to 100%, OR Formulation 2: concentrated ammonia solution 3 - 8%; liquid detergent 0.2 - 2%; water to make up to 100%. If ammonia is used, use good ventilation to prevent vapor exposure. Contact your supplier for clean-up assistance. See Section 13, Disposal Considerations, for additional information.7. HANDLING AND STORAGEPrecautions for safe handling: Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Avoid breathing vapor. Wash thoroughly after handling. Use with adequate ventilation. Keep container closed. This material is hygroscopic in nature. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. Spills of these organic materials on hot brous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.Conditions for safe storage: Store in a dry place. Protect from atmospheric moisture. Do not store product contaminated with water to prevent potential hazardous reaction. See Section 10 for more specic information. Additional storage and handling information on this product may be obtained by calling your sales or customer service contact.Storage stabilityStorage temperature: Storage Period:15 - 35 °C (59 - 95 °F) 6 Month
FlexRock Coatings™ Part B Page 6Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART B8. EXPOSURE CONTROLS / PERSONAL PROTECTIONControl parametersExposure limitsComponent Regulation Type of listing Value/Notation4,4’-Methylenediphenyl diisocyanate Dow IHG TWA 0.005 ppmDow IHG STEL 0.02 ppmACGIH TWA 0.005 ppmOSHA Z-1 C 0.2 mg/m3 0.02 ppmExposure controlsEngineering controls: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. Exhaust systems should be designed to move the air away from the source of vapor/aerosol generation and people working at this point. The odor and irritancy of this material are inadequate to warn of excessive exposure.Individual protection measuresEye/face protection: Use chemical goggles.Skin protectionHand protection: Use gloves chemically resistant to this material. Examples ofpreferred glove barrier materials include: Butyl rubber. Polyethylene. Chlorinated polyethylene. Ethyl vinyl alcohol laminate (“EVAL”). Examples of acceptable glove barrier materials include: Viton. Neoprene. Polyvinyl chloride (“PVC” or “vinyl”).Nitrile/butadiene rubber (“nitrile” or “NBR”). NOTICE: The selection of a specic glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specications provided by the glove supplier. Other protection: Use protective clothing chemically resistant to this material. Selection of specic items such as face shield, boots, apron, or full body suit will depend on the task.Respiratory protection: Atmospheric levels should be maintained below the exposure guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator equipped with an organic vapor sorbent and a particle lter. For situations where the atmospheric levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or for situations where the atmospheric level is unknown, use an approved positive-pressure self-contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply.The following should be effective types of air-purifying respirators: vapor cartridge with a particulate pre-lter.
FlexRock Coatings™ Part B Page 7Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART B9. PHYSICAL AND CHEMICAL PROPERTIESAppearancePhysical state Liquid. Color Brown Odor MustyOdor Threshold 0.4 ppm Based on Literature for MDI. Odor is inadequate warning of excessive exposure.pH Not applicableMelting point/range Not applicableFreezing point forms crystals below 10ºC LiteratureBoiling point (760 mmHg) decomposes prior to boilingFlash point closed cup >204 °C ( 399 °F) LiteratureEvaporation Rate (Butyl Acetate=1) No test data availableFlammability (solid, gas) Not ApplicableLower explosion limit No test data availableUpper explosion limit No test data availableVapor Pressure < 0.00001 mmHg at 25 °C (77 °F) LiteratureRelative Vapor Density (air = 1) 8.5 Literature Relative Density (water = 1) 1.23 at 25 °C (77 °F) / 25 °C LiteratureWater solubility insoluble, reacts, evolution of CO2Partition coefcient: n- Reacts with water. Octanol/water Auto-ignition temperature >600 °C (1,112 °F) LiteratureDecomposition temperature No test data availableDynamic Viscosity 160 - 240 mPa.s at 25 °C (77 °F) ASTM D4889Kinematic Viscosity No test data availableExplosive properties Not explosiveOxidizing properties NoMolecular weight No test data availableNOTE: The physical data presented above are typical values and should not be construed as a specification10. STABILITY AND REACTIVITYReactivity: Diisocyanates react with many materials and the rate of reaction increases with temperature as well as increased contact; these reactions can become violent. Contact is increased by stirring or if the other material mixes with the diisocyanate. Diisocyanates are not soluble in water and sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat.Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
GreenKoat™ Part B Page 8Safety Data SheetGreenKoat Surface Coating SystemFlexRock Coatings™ | PART BPossibility of hazardous reactions: Can occur. Exposure to elevated temperatures can cause product to decompose and generate gas. This can cause pressure build-up and/or rupturing of closed containers. Polymerization can be catalyzed by: Strong bases. Water.Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Generation of gas during decomposition can cause pressure in closed systems. Pressure build-up can be rapid. Avoid moisture. Material reacts slowly with water, releasing carbon dioxide which can cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this reaction.Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases. Metal compounds. Moist air. Strong oxidizers. Diisocyanates react with many materials and the rate of reaction increases with temperature as well as increased contact; these reactions can become violent. Contact is increased by stirring or if the other material mixes with the diisocyanate. Diisocyanates are not soluble in water and sink to the bottom, but react slowly at the interface. The reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat. Avoid contact with metals such as: Aluminum. Zinc. Brass. Tin. Copper. Galvanized metals. Avoid contact with absorbent materials such as: Moist organic absorbents. Avoid unintended contact with polyols. The reaction of polyols and isocyanates generate heat.Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Gases are released during decomposition.11. TOXICOLOGICAL INFORMATIONAcute toxicityAcute Oral Toxicity: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury.Typical for this family of materials.LD50, Rat, > 10,000 mg/kgAcute Dermal Toxicity: Prolonged skin contact is unlikely to result in absorption of harmful amounts.Typical for this family of materials.LD50, Rabbit, > 9,400 mg/kgAcute Inhalation Toxicity: At room temperature, vapors are minimal due to low volatility. However, certain operations may generate vapor or mist concentrations sufcient to cause respiratory irritation and other adverse effects. Such operations include those in which the material is heated, sprayed or otherwise mechanically dispersed such as drumming, venting or pumping. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (uid in the lungs.) Effects may be delayed. Decreased lung function has been associated with overexposure to isocyanates.
FlexRock Coatings™ Part B Page 9Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BLC50, Rat, 4 Hour, dust/mist, 0.49 mg/lFor similar material(s): 4,4’-Methylenediphenyl diisocyanate (CAS 101-68-8).LC50, Rat, 1 Hour, Aerosol, 2.24 mg/lFor similar material(s): 2,4’-Diphenylmethane diisocyanate (CAS 5873-54-1).LC50, Rat, 4 Hour, Aerosol, 0.387 mg/lSkin corrosion/irritation: Prolonged contact may cause slight skin irritation with local redness. May stain skin.Serious eye damage/eye irritation: May cause moderate eye irritation. May cause slight temporary corneal injury.Sensitization: Skin contact may cause an allergic skin reaction. Animal studies have shown that skin contact with isocyanates may play a role in respiratory sensitization.May cause allergic respiratory reaction: Reexposure to extremely low isocyanate concentrations may cause allergic respiratory reactions in individuals already sensitized. Asthma-like symptoms may include coughing, difcult breathing and a feeling of tightness in the chest. Occasionally, breathing difculties may be life threatening. Effects may be delayed.Specic Target Organ Systemic Toxicity (Single Exposure) May cause respiratory irritation.Route of Exposure: InhalationTarget Organs: Respiratory TractSpecic Target Organ Systemic Toxicity (Repeated Exposure)Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after repeated excessive exposures to MDI/polymeric MDI aerosols.CarcinogenicityLung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory irritation and lung injury. Current exposure guidelines are expected to protect against these effects reported for MDI.TeratogenicityIn laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother.Reproductive toxicityNo relevant data found.
FlexRock Coatings™ Part B Page 10Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BMutagenicityGenetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative.Aspiration HazardBased on physical properties, not likely to be an aspiration hazard.12. ECOLOGICAL INFORMATIONToxicityAcute toxicity to sh. The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).LC50, Danio rerio (zebra sh), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or EquivalentAcute toxicity to aquatic invertebratesEC50, Daphnia magna (Water ea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plantsNOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/l, OECD Test Guideline 201 or EquivalentToxicity to bacteriaEC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/lToxicity to soil-dwelling organismsEC50, Eisenia fetida (earthworms), 14 d, > 1,000 mg/kgToxicity to terrestrial plantsEC50, Avena sativa (oats), Growth inhibition, 1,000 mg/lEC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/lPersistence and degradabilityBiodegradability: In the aquatic and terrestrial environment, material reacts with water forming predominantly insoluble polyureas which appear to be stable. In the atmospheric environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates.10-day Window: Not applicableBiodegradation: 0 % Exposure time: 28 d
FlexRock Coatings™ Part B Page 11Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BMethod: OECD Test Guideline 302C or EquivalentBioaccumulative potentialBioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 dDiphenylmethane Diisocyanate, isomers and homologuesBioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d4,4’-Methylenediphenyl diisocyanateBioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 dMobility in soil. In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.13. DISPOSAL CONSIDERATIONSDisposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN SDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional information, refer to: Handling & Storage Information, SDS Section 7 Stability & Reactivity Information, SDS Section 10 Regulatory Information, SDS Section 1514. TRANSPORT INFORMATIONDOTProper shipping name Environmentally hazardous substance, liquid, n.o.s.(MDI)UN number UN 3082Class 9Packing group IIIReportable Quantity MDIClassication for SEA transport (IMO-IMDG): Not regulated for transport
FlexRock Coatings™ Part B Page 12Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BTransport in bulk Consult IMO regulations before transporting ocean bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC CodeClassication for AIR transport (IATA/ICAO):Not regulated for transportThis information is not intended to convey all specic regulatory or operational requirements/information relating to this product. Transportation classications may vary by container volume and may be inuenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material.15. REGULATORY INFORMATIONSuperfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312Acute toxicity (any route of exposure)Skin corrosion or irritationSerious eye damage or eye irritationRespiratory or skin sensitisationSpecic target organ toxicity (single or repeated exposure)Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372.Components CASRNDiphenylmethane Diisocyanate, isomers and homologues 9016-87-94,4’-Methylenediphenyl diisocyanate 101-68-8Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)Section 103Calculated RQ exceeds reasonably attainable upper limit. Components CASRN RQ (RCRA Code)4,4’-Methylenediphenyl diisocyanate 101-68-8 5000 lbs RQPennsylvania Worker and Community Right-To-Know Act:To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this statute.
FlexRock Coatings™ Part B Page 13Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BCalifornia Prop. 65This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.United States TSCA Inventory (TSCA)All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.16. OTHER INFORMATIONPREPARED BY: GreenKoat Solutions LLCDATE: Updated January 2021MANUFACTURER DISCLAIMER: The information contained herein is based on data believed to be reliable by GreenKoat, LLC. It is true and accurate to the best of our knowledge, but is not intended to be all inclusive. Users should consider this information as a supplement to other information gathered by them and must make their own determination of suitability and completeness to assure proper safe use and disposal of these materials.ACGIH USA. ACGIH Threshold Limit Values (TLV)C CeilingDow IHG Dow Industrial Hygiene GuidelineOSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air ContaminantsSTEL Short term exposure limitTWA Time weighted averageFull text of other abbreviationsAICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identication System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea ExistingChemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a testpopulation (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA- Mine Safety and Health Administration; n.o.s. - Not Otherwise Specied; NFPA - National Fire Protection Association;
FlexRock Coatings™ Part B Page 14Safety Data SheetFlexRock Coatings SystemFlexRock Coatings™ | PART BNO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Ofce of Chemical Safety and Pollution Prevention;PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and ChemicalSubstances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act;REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating DecompositionTemperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan ChemicalSubstance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United NationsRecommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very BioaccumulativeDISCLAIMER: THE INFORMATION HERE IN IS BASED ON THE DATA AVAILABLE AND IS BELIEVED TO BE ACCURATE, HOWEVER, THE MANUFACTURER MAKES NO WARRANTY EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS OBTAINED FROM THE USE THEREOF. ACCORDINGLY, WE ASSUME NO RESPONSIBILITY FOR INJURY FROM THE USE OF THIS PRODUCT.