GET COATED Exterior Deck TopCoatinfo@flexrockcoatings.com | 800-808-0414 | FlexRockCoatings.comFX-866T UrethaneFX-866T CLEARSAFETY DATA SHEET1
PRODUCT NAME/CODE: FX-866T, ClearMANUFACTURER: National Polymers Inc.STREET ADDRESS: 9 Guttman AvenueCITY, STATE, ZIP: Charleroi, Pa. 15022 INFORMATION PHONE: 724-483-9300 EMERGENCY PHONE: Chemtrec 800-424-9300 FAX PHONE: 724-483-9306PREPARED BY: Harry JacksonDATE REVISED: 4/26/19Chemical Name or Class: Alaphatic Urethane Pre-polymer mixtureSECTION 2: HAZARDS IDENTIFICATION Hazard Overview GHS Classification: Acute oral toxicity category 4, Respiratory sensitizer category 1, Skin sensitizer category 1, Flammable liquid category 3, Specific target organ toxicity single exposure category 3, Specific target organ toxicity following repeated exposure category 1, Skin corrosion/irritation category 2, Toxic to reproduction category 2, Germ cell Mutagenicity category 1B, Serious Eye damage/Irritation Category 2A, Carcinogenicity category 1a, Acute hazard to aquatic environment category 3, Chronic hazards to aquatic environment category 2 GHS Label Elements and Precautionary Statements: Label Elements: Flame, Health Hazard Exclamation Mark, Aquatic Toxicity,Hazard Statements: Warning: Harmful if swallowed.Danger: May cause allergy or asthma symptoms or breathing difficulties if inhaled.Warning: May cause an allergic skin reaction.Warning: Flammable Liquid and Vapour.Warning: May cause respiratory irritation.Danger: Causes damage to organs through prolonged or repeated exposure.Warning: Causes skin irritation.Warning: Suspected of damaging fertility or the unborn child.Danger: May cause genetic defects.Warning: Causes serious eye irritation.Danger: May cause cancer.Harmful to aquatic lifeToxic to aquatic life with long lasting effects.Precautionary statements: P102 Keep out of reach of children.P103 Read label before useP261 Avoid breathing dust/fume/gas/mist/vapours/sprayP284 Wear respiratory protection.P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.P233 Keep container tightly closed.P272 Contaminated work clothing should not be allowed out of the workplace.P280 Wear protective gloves and clothing to prevent skin contact.P240 Ground/bond container and receiving equipment.P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.P242 Use only non-sparking tools.P243 Take precautionary measures against static discharge.P280 Wear protective gloves/protective clothing/eye protection/face protection.P261 Avoid breathing dust/fume/gas/mist/vapours/sprayP271 Use only outdoors or in a well-ventilated area.P260 Do not breathe dust/fume/gas/mist/vapours/spray.P264 Wash hands thoroughly after handling.P270 Do not eat, drink or smoke when using this product.FX-866T, High Solids, Moisture-Cured, Industrial Maintenance Coating, Clear2
P201 Obtain special instructions before use.P202 Do not handle until all safety precautions have been read and understood.P273 Avoid release to the environment.Response P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.P342 + P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.P370 + P378 In case of fire: Use ALCOHOL FOAM, CO2, DRY CHEMICAL for extinctionP304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.P312 Call a POISON CENTER or doctor/physician if you feel unwell.P314 Get medical advice/attention if you feel unwell.P301 + P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.P330 Rinse mouth.P302 + P352 IF ON SKIN: wash with plenty of soap and water.P333 + P313 IF SKIN irritation or rash occurs: Get medical advice/attention.P362 + P364 Take off contaminated clothing and wash it before reuse.P308 + P313 IF exposed or concerned: Get medical advice/attention.P305 + P351 + P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.P337 + P313 IF eye irritation persists: Get medical advice/attention.P391 Collect spillage.Storage: P403 + P235 Store in a well-ventilated place. Keep cool.P405 Store locked up.P403 + P233 Store in a well-ventilated place. Keep container tightly closed.Disposal: P501 Dispose of contents/container to a waste disposal facility in accordance with local, state federal or international lawsOther non-classifiable hazards based on ingredients: Acute inhalation toxicity category 2 HMIS HAZARD CLASSIFICATION HEALTH: 2 FLAMMIBILITY: 2 REACTIVITY: 1 PERSONAL PROTECTIVE EQUIPMENT: G POTENTIAL HEALTH EFFECTS EYES: Can cause irritation, redness, tearing, or blurred vision as well as corneal opacity and conjunctivitis.SKIN: May cause irritation, defatting and dermatitis.INGESTION: Can cause gastrointestinal irritation, nausea, vomiting, diarrhea and aspiration of material into the lungs can cause chemicalpneumonitis which can be fatal. Can cause corrosive action to mucous membranes and digestive tract.INHALATION: Can cause nausea and respiratory irritation, dizziness, weakness, fatigue, headache and possible unconsciousness. Burningsensation to mucous membranes, shortness of breath and flu like symptoms may occur.HEALTH HAZARDS (ACUTE AND CHRONIC): Can cause sensitization by exposure through contact or high concentrations of vapor. Overexposure can possibly cause anemia.Liver abnormalities, kidney damage or eye damage. May cause asthma or other respiratory disorders, bronchitis, emphysema,hyperactivity and eczema. Chronic Inhalation: as a result of previous repeated overexposures or a single large dose, certainindividuals will develop isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanateat levels well below the TLV or MGL. These symptoms, which include chest tightness, wheezing, cough, shortness of breath orasthma attack, could be immediate or delayed up to several hours after exposure. Similar to many nonspecific asthmatic responses,there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air, or otherirritants. This increased lung sensitivity can persist for weeks and in several years. Chronic overexposure to isocyanates has beenreported to cause lung damage, including decrease in lung function, which may be permanent. Sensitization may either betemporary or permanent. Acute skin Contact: Isocyanates react with the skin protein and moisture and can cause irritation.Symptoms of skin irritation may be reddening, swelling, rash, scaling, or blistering. Some persons may develop skin sensitizationfrom skin contact. Cured material is difficult to remove.Chronic Skin contact: Prolonged contact with the isocyanate can cause reddening, swelling, rash, scaling, or blistering. In those whohave developed a skin sensitization, these symptoms can develop as a result of contact with very small amounts of liquid material oreven as a result of vapor-only exposure.FX-866T, High Solids, Moisture-Cured, Industrial Maintenance Coating, Clear3
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: RESPIRATORY CONDITIONS OR OTHER ALLERGIC RESPONSE.CARCINOGENICITY OSHA: no NTP: no IARC: no ADDITIONAL CARCINOGENICITY INFORMATION: No dataSECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT CAS NO. OSHA PEL ACGIH TLV OSHA STEL WEIGHT % 1-Methoxy-2-Propyl Acetate 108-65-6 100ppm 100ppm NONE 10-304-chlorobenzotrifluoride 98-56-6 100ppm 100 ppm NONE 5-15Aliphatic Isocyanate 5124-30-1 0.005ppm 0.005ppm NONE <0.5Aliphatic Urethane Prepolymer Non available NONE NONE NONE 60-100SECTION 3 NOTES: *** Indicates toxic chemical(s) subject to reporting requirements of section 313 of Title III and of 40 CFR 372. Note: Ingredients listed without percentages, the percentages are considered a trade secret. Information concerning non-hazardousingredients are considered a trade secret._________________________________________________________________________________________________________SECTION 4: FIRST AID MEASURESEYES: Flush eyes with water for at least fifteen minutes and consult a physician.SKIN: For extreme exposure use a safety shower immediately. Wash affected skin with soap and water and remove all contaminatedclothing promptly.INGESTION: If swallowed, contact a physician immediately. Do not induce vomiting. Decision to induce vomiting should only be made by aphysician. Never give anything by mouth to an unconscious person. INHALATION: Remove victim to fresh air and administer oxygen if necessary. Obtain medical assistance. Asthmatic type symptoms may occurimmediately or be delayed for several hours. Treatment is symptomatic.NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: This product contains aromatic and aliphatic hydrocarbon solvents and aliphatic isocyanate. SECTION 5: FIRE FIGHTING MEASURES FLAMMABLE LIMITS IN AIR, UPPER: 13 percent (% by volume) LOWER: 1 percent FLASH POINT: 110F METHOD USED: Closed cup EXTINGUISHING MEDIA: Foam, alcohol foam, co2, dry chemicalSPECIAL FIRE FIGHTING PROCEDURES: Do not enter confined fire area without full bunker gear including a positive pressure NIOSH approved self-contained breathingapparatus. Presence of solvents in products may require grounding. Remove all sources of ignition.UNUSUAL FIRE AND EXPLOSION HAZARDS: If fire occurs, solvents may produce excessive pressure. Sealed drums may rupture and ignite. Vapors are heavier than air andmay travel along the ground and ignite by any source of ignition. During a fire, TDI vapors and other toxic gasses may be evolvedsuch as CO, CO2, N2O, HCN, unburned hydrocarbons, and toxic fumes.FX-866T, High Solids, Moisture-Cured, Industrial Maintenance Coating, Clear4
SECTION 6: RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Personnel Safeguards: Immediately evacuate all non-essential personnel to safe places. Emergency responders should wearpositive pressure supplied air respirator with full face piece and proper protective gear before entering the affected area.Regulatory Notifications: Waste of this product is defined as hazardous according to U.S. EPA. Spill reporting requirements andreportable quantities vary by region. Consult all applicable state and local regulations. For Canada, observe all precautions notedabove.Containment and Clean-up: Remove all sources of ignition. Provide ventilation. Respiratory protection is recommended during spillclean-up. Stop leak if possible without risk. Prevent liquids from entering sewers, drains or waterways by diking with sand or earth.Absorb with vermiculite or other absorbent material, then flush area with decontamination solution. Put in open drums. Treat andclean with decontamination solution consisting of water containing 4-8% ammonia and 2% detergent.SECTION 7: HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool dry place. Seal all partially used containers. Wash with soap and water before eating, drinking, smoking or usingtoilet facilities. Mixed materials contain the hazards of all the components, therefore, read the SDS’s of all the components prior to using material. Properly label all containers. Keep material away from all sources of ignition. Wear appropriate safety equipmentand protective clothing.OTHER PRECAUTIONS: Avoid all skin contact. Avoid breathing vapors generated from the material. Observe conditions of good general hygiene and safeworking practices. Contaminated leather articles cannot be cleaned and must be discarded if contaminated with this product. Washall contaminated clothing prior to the reuse thereof. Wear appropriate safety equipment and respirator at all times when ventilationis not sufficient to control vapors. Observe OSHA regulations for respirator use (29 CFR 1910.134). When spraying material avoidexposure to all mists generated by using air supplied respirator.SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION RESPIRATORY PROTECTION: Use a NIOSH approved respirator as required to prevent over exposure to vapor in accordance with 29 CFR 1910.134. Engineeringor administrative measures should be taken to reduce the risk and exposure. Use a positive pressure supplied air respirator whenexceeding TLV’s or if TDI monomer concentrations exceed acceptable limits of when spraying material.VENTILATION: Exhaust ventilation sufficient to keep airborne concentrations of TDI below their TLV and MGI maximum. Refer to Patty’s industrial hygiene and toxicology – volume 1 (3rd edition) chapter 17 and volume III (1st edition) chapter 3 for detailsPROTECTIVE GLOVES: Impervious gloves – neoprene or rubberEYE PROTECTION: Splash goggles or glasses with side shields. Do not wear contact lenses when using this product.OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Wear body covering clothing and other coverings as necessary such as apron and appropriate footwear to avoid contact withmaterial.WORK HYGIENIC PRACTICES: Observe good general hygienic practices.Exposure Limits and GuidelinesComponentCAS No.Exposure Limit1-methoxy-2-propyl acetate108-65-60.05 mg/m3 TWA, NIOSHAliphatic iisocyanate5024-30-10.005ppm OSHA PELparochlorobenzotrifluoride98-56-6100ppm ACGIH TWASEE SECTION THREE FOR ADDITIONALOCCPATIONAL EXPOSURE LIMIT VALUES. 5
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: High viscosity liquid with typical solvent odor.BOILING POINT OR RANGE: 284-500 FVAPOR DENSITY (AIR = 1): Not Determined SPECIFIC GRAVITY (H2O = 1): 1.1 EVAPORATION RATE: Not Determined SOLUBILITY IN WATER: Negligible Odor Threshhold: Not Determined pH: Not Applicable Melting point/freezing point: Not determined Vapor Pressure: 3.7 mm Hg @ 20C Auto Ignition Temperature: Not determined Partition Coefficient: n-octanol/water: Not determined Decomposition Temperature: Not determined SECTION 10: STABILITY AND REACTIVITY STABILITY: StableCONDITIONS TO AVOID (STABILITY): Avoid excessive heat or open flames as well as all sources of ignition such as sparks, heaters, and static discharges etc.INCOMPATIBILITY (MATERIAL TO AVOID): Avoid water, amines, strong bases, alcohols, metal compounds, and surface active compounds.HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: May form toxic chemicals, carbon dioxide, carbon monoxide, oxides of nitrogen, HCN and HDIHAZARDOUS POLYMERIZATION: Moisture of materials that react with isocyanates and temperatures above 400 degrees f may cause polymerization.SECTION 11: TOXICOLOGICAL INFORMATION Primary Eye Irritation: IrritatingPrimary Skin Irritation: IrritatingAcute Dermal Toxicity: Not availableSubacute Dermal Toxicity:Not availableDermal Sensitization: Not availableInhalation Toxicity: Not availableInhalation Sensitization: Not availableOral Toxicity: Mutagenicity: Not availableCarcinogenicity: Diisocyanates are suspect carcinogens. When ingested, diisocyanates have caused cancer in certain animals.Reproductive Toxicity: Not availableTeratogenicity: Not available Immunotoxicity: Not availableNeurotoxicity: Not availableNo other toxicological information available SECTION 12: ECOLOGICAL INFORMATION Aquatic Toxicity: Not known.Terrestrial Toxicity: Not knownChemical Fate and Transport: Not known.No other ecological information available 6
SECTION 13: WASTE DISPOSAL WASTE DISPOSAL METHOD: Dispose of the material in a waste disposal site in accordance with local, state, and federal law.SECTION 14: Transport Information DOT: UN1263, Paint (CONTAINS 1-Methoxy-2-Propyl Acetate), 3, PG III, Marine Pollutant Other: Not regulated for non-bulk domestic ground shipments for packaging of 450 liters (119 gallons) or less (DOT 49CFR 173.150(f)).IMO/IMDG: UN1263, Paint (CONTAINS 1-Methoxy-2-Propyl Acetate), 3, PG III, Marine Pollutant SECTION 15: REGULATORY INFORMATION Regulatory Lists U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory or exempt from listing on the TSCA Inventory.SARA 311/312 Categories Acute: Yes Chronic: Yes Fire: Yes Pressure: Yes Reactive: YesThis product contains the following Sara, Title III, Section 313 Chemicals: Aliphatic Diisocyanate CAS# 5124-30-0 Regulatory List for State: FL, MA, MN, PA, RICalifornia Proposition 65 Information: Warning! This product contains detectable components, including the followingcomponents, which are substances or belong to classes of substances known to the State of California to cause cancer, birthdefects and/or other reproductive harm.Aliphatic Diisocyanate CAS# 5124-30-0 Canadian Regulations DSL/NDSL: The components of this product are listed on the Canadian Domestic Substances List (DSL) or Non-DomesticSubstance List (NDSL).WHMIS Hazard Class: B3 D2AThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDScontains all the information required by the CPR.Other Regulations: No other information available SECTION 16: OTHER INFORMATION DISCLAIMER: The information Contained herein is based on the data available and is believed to be accurate. However, the manufacturer makes no warranty expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Accordingly, we assume no responsibility for injury from the use of this product. N/A = Not Available See Section 1 for date of preparation FX-866T, High Solids, Moisture-Cured, Industrial Maintenance Coating, Clear7